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Okazaki, Hiroyuki*; Idesaki, Akira*; Koshikawa, Hiroshi*; Matsumura, Daiju; Ikeda, Takashi*; Yamamoto, Shunya*; Yamaki, Tetsuya*
Journal of Physical Chemistry C, 127(49), p.23628 - 23633, 2023/12
Times Cited Count:0 Percentile:0(Chemistry, Physical)Liu, B.*; Feng, R.*; Busch, M.*; Wang, S.*; Wu, H.*; Liu, P.*; Gu, J.*; Bahadoran, A.*; Matsumura, Daiju; Tsuji, Takuya; et al.
ACS Nano, 16(9), p.14121 - 14133, 2022/09
Times Cited Count:51 Percentile:98.66(Chemistry, Multidisciplinary)Kimata, Tetsuya*; Kakitani, Kenta*; Yamamoto, Shunya*; Shimoyama, Iwao; Matsumura, Daiju; Iwase, Akihiro*; Mao, W.*; Kobayashi, Tomohiro*; Yamaki, Tetsuya*; Terai, Takayuki*
Physical Review Materials (Internet), 6(3), p.035801_1 - 035801_7, 2022/03
Times Cited Count:7 Percentile:68.86(Materials Science, Multidisciplinary)Cui, Y.-T.*; Harada, Yoshihisa*; Niwa, Hideharu*; Oshima, Masaharu*; Hatanaka, Tatsuya*; Nakamura, Naoki*; Ando, Masaki*; Yoshida, Toshihiko*; Ishii, Kenji*; Matsumura, Daiju
NanotechJapan Bulletin (Internet), 11(4), 6 Pages, 2018/08
no abstracts in English
Saito, Akinori*; Tsuji, Hiromi*; Shimoyama, Iwao; Shimizu, Kenichi*; Nishina, Yuta*
Chemical Communications, 51(27), p.5883 - 5886, 2015/04
Times Cited Count:13 Percentile:40.21(Chemistry, Multidisciplinary)no abstracts in English
Konishi, Satoshi; Hara, Masahide*; Okuno, Kenji
Fusion Technology, 28(3), p.652 - 657, 1995/10
no abstracts in English
Ota, Tomonori*; Hagiwara, Tokio*; Sugimoto, Masaki; Yamamoto, Shunya; Koshikawa, Hiroshi; Yamaki, Tetsuya
no journal, ,
Nitrogen (N)-doped carbon-based electrocatalysts are expected as a platinum alternative material for cost reduction of polymer electrolyte membrane fuel cells. However, nobody has not yet established the method of introducing N atoms in a graphene structure at high concentrations. Therefore, our purpose is to propose a new method of N doping using electron beam irradiation at high temperatures in an ammonia atmosphere. We developed here a sample chamber with a heating device, gas inlet and outlet, which made it possible to perform the irradiation without any temperature change. As a result, the phenolic resin, that is, a source of carbon-based electrocatalysts was irradiated with 2 MeV electrons at a dose rate of 2 kGy/s while being maintained at 300 C with a high precision as 2 C.
Ota, Tomonori*; Yamaki, Tetsuya; Sugimoto, Masaki; Yamamoto, Shunya; Koshikawa, Hiroshi; Hagiwara, Tokio*
no journal, ,
Nitrogen-doped carbon-based catalysts are expected as Pt alternatives, and however there have been so far no established methods to introduce N atoms into graphene structures. Thus, we report N doping in carbon-based catalysts by electron beam (EB) irradiation in ammonia (NH). A precursor was phenolic resin or its mixture with 5 or 10 wt% cobalt(II) chloride (CoCl); it was then irradiated with 2 MeV electron beam up to a dose of 6 MGy in 1 vol% NH at 400C. This irradiated powder was carbonized in an Ar atmosphere at 800C for 1 h. An N-doping level reached an atomic concentration of ca. 0.5% when 5 wt% CoCl was mixed in the precursor.
Sugimoto, Masaki; Ota, Tomonori*; Yamamoto, Shunya; Koshikawa, Hiroshi; Yamaki, Tetsuya; Hagiwara, Tokio*
no journal, ,
no abstracts in English